UNIVERSIDAD TÉCNICA DE MACHALA FACULT FACULTAD AD DE CIENCIAS AGROPECUARIAS ESCUELA DE INGENIERÍA AGRONÓMICA CÁTEDRA: QUÍMICA AGRÍCOLA PROFESOR: DR. PATRICIO REYES ALUMNO: PABLO ERNESTO VILLA GUERRERO CICLO: CUARTO “A” FECHA: MIÉRCOLES, ! DE DICIEMBRE DEL "!! INFORME: # TEMA:
DETERMINACIÓN DE LA DUREZA (AGUA)
MACHALA $ EL ORO % ECUADOR "!" % "!!
I. INTRODUCCIÓN E&'( E&'( (& )* '+'+- // 0( 1-/ 1-/+ +'/ '/+2/ +2/,, +(1 +(123 230 0// 4/+ 4/+ 1/& 1/& 1)5 1)5*/ */&& 0(1 0(1 6)+ 6)+'/ '/ 6261 6261// 0( 2*7(*2(+8 7+/*9526, (1 6)1 6/*&2&'29 (* (&'-1(6(+ 1 0)+(3 0(1 7) 5(02*'( )* 4+/6(&/ 0( '2')1629* 6/* EDTA 7+;25('+8 &8 /-'(*(+ 6*'200 0( 1& &1(& 0( 6+-/*'/ 0( 6162/ 57*(&2/ 0( 1 +(&4(6'2; 5)(&'+. E&'( '+-/ (& 0( 5)6< 254/+'*62, 4/+=)( '(*(5/& 6/*'6'/ 6/* 1 +(1200 <(5/& &(7)+0/ 5/+ 4+(*023( '+;>& 0( 1 4+?6'26, 1/7+*0/ &)4(++ 62(+'& 0)0& &/-+( (1 '(5 '+'0/ 5(02*'( &(*6211/& 4+/6(&/& 0('(+52*+ 1 0)+(3 0(1 7). E* (&'( '+-/ &( <* 41*'(0/ 1/& &27)2(*'(& /-('2;/&: ‐ ‐ ‐ ‐
D('(+52*+ 1 0)+(3 '/'1 0( 1& 02@(+(*'(& 5)(&'+& 0( 7)&. E&'-1(6(+ 1 0)+(3 0(1 6162/ 0( 1& 02@(+(*'(& 5)(&'+& 0( 7)&. O-'(*(+ 1 0)+(3 0(1 57*(&2/ 0( 1& 1 & 02@(+(*'(& 5)(&'+& 0( 7)&. I*'(+4+('+ 1 0)+(3 0( 1& 02@(+(*'(& 5)(&'+& 0( 7)&.
E&'( '+-/ &( 1/ 11(;9 6-/ (* (1 L-/+'/+2/ 0( Q)8526 0( 1 F6)1'0 0( C2(*62& A7+/4(6)+2& 0( 1 U*2;(+&200 T>6*26 0( M6<1, (1 08 !# 0( 0262(5-+( 0(1 "!!.
II. REVISIÓN LITERARIA 2.1. DUREZA DEL AGUA BARRO, G ! A@2+5 =)( 1 0)+(3 0( 1& 7)& *')+1(& (& 4+/0)620 &/-+( '/0/ 4/+ 1& &1(& 0( 6162/ 57*(&2/, (* 5(*/+ 4+/4/+629* 4/+ (1 <2(++/, (1 1)52*2/ /'+/& 5('1(&. L =)( &( 0(-( 1/& -26+-/*'/& 6+-/*'/& 0( 6162/ 57*(&2/ &( 0(*/52* 0)+(3 '(54/+1 4)(0( (1252*+&( 4/+ (-)112629*, =)( 1 52&5/ '2(54/ (&'( (&'(+21 +2123 23 (1 7) 7).. L 0)+( 0)+(3 3 +(&2 +(&20) 0)1 1 &( 6/*/ 6/*/6( 6( 6/5/ 6/5/ 0)+( 0)+(3 3 */ 6+6+-9* 9*26 26 / 4(+5*(*'(. L& 7)& =)( 4/&((* (&' 0)+(3 4)(0(* -1*0+&( 02(*0/ 6+-/*'/ 0( &/02/ 61, / @21'+?*0/1& '+;>& 0( 6(/12'& *')+1(& / +'2@2621(& =)( -&/+-(* 1/& 2/*(& 5('?126/& =)( 4+/0)6(* 1 0)+(3, 12-(+* 2/*(& &/02/ (* (1 7). L 0)+(3, 4/+ 1/ 7(*(+1, &( (4+(& 6/5/ (1 *5(+/ (=)2;1(*'( 0( 52127+5/& 0( 6+-/*'/ 0( 6162/ CCO 4/+ 12'+/. JIMMER, F M6CALLION, K !, 2*026* =)( 1 0)+(3 (& 1 &/1)629* (* 7) '*'/ 0( 6162/ 6/5/ 0( 0( 57*(&2/ (* @/+5 0( 6'2/*(&, 2*0(4(*02(*'(5(*'( 0( 1 *')+1(3 0( 1/& *2/*(& 4+(&(*'(&. E&' &( < (4+(&0/, 4/+ 1/ 7(*(+1, (* @)*629* 0(1 6+-/*'/ 0( 6162/, CCO . IIGUE, M ! @2+5 =)( (* 7)& +26& (* 2/*(& -26+-/*'0/& < 1 '(*0(*62 0(1 6162/ 0(1 57*(&2/ 4+(6242'+&( (* @/+5 0( 6+-/*'/& 5(020 =)( 1 &/1)629* 0(1 &)(1/ &( ;)(1;( 5?& 6/*6(*'+0. E&' +(6629* */ &( 6/541(5(*' '/' '/'15 15(* (*'( '( (* 62+6 62+6)* )*&' &'* *62 62& & /+02 /+02* *+2 +2&, &, 4(+/ 4(+/ 5(02 5(020 0 =)( =)( '2(* '2(*(* (* 1)7 1)7+, +, 1& 1& 6/*6(*'+62/*(& 0( 6162/ 57*(&2/ &( +(0)6(*, )5(*'*0/ 1 4+/4/+629* +(1'2; 0( &/02/. KENJINS, D. ('. 1. !, 0('11* =)( 1 0)+(3 (& )* 4+/42(00 /6&2/*0 4/+ 1 4+(&(*62 0( 6'2/*(& 5('?126/& 4/12;1(*'(&. S( 5*2@2(&' 4/+ +(662/*(& (*'+( 1/& 6'2/*(& 0( 0)+(3 1/& -/*(& -/*(& =)( @/+5* 4+(6242'0/ (*'+( 1/& 6'2/*(& 0( 0)+(3 62(+'/& *2/*(& 4/+ ((541/, SO #$, CO$ 4+ @/+5+ 2*6+)&'62/*(&. L 0)+(3 0( 1& 7)& *')+1(& &( 0(-( (* 7+* 4+'( 1/& *2/*(& C M7. C/* @+(6)(*62 1 0)+(3 &( 520( '+;>& '+ ;>& 0( 1 4126629* 0(1 4+2*6242/ 0( =)(1629*.
2.2. UNIDAD DE LA DUREZA JIMMER, F M6CALLION, K !, (4126* =)( 1 0)+(3 &( < (4+(&0/, 4/+ 1/ 7(*(+1, (* @)*629* 0(1 6+-/*'/ 0( 6162/, CCO , 4)(&'/ =)( (1 4(&/ 5/1(6)1+ 0(1 CCO (& !"" &) 4(&/ (=)2;1(*'( (& ", 4+/4/+62/**0/ )* )*200 6/*;(*2(*'( 0( 2*'(+65-2/ 4+ (4+(&+ '/0/& 1/& 2/*(& (* 7), (* ;(3 0( 5/&'++ 60 )*/ 0( (11/& 6/* &) 4+/42/ 4(&/ (=)2;1(*'(.
2.3. ORIGEN DE LA DUREZA JIELY, G ! 2*026 =)( (1 7) &)-'(++?*( =)( 4& '+;>& 0( 1 6123 02&)(1;( 1/& 6/54)(&'/& 0( 6162/ 57*(&2/ =)( 4+/;/6* 1 0)+(3. E* 6/*&(6)(*62&, 1& 7)& &/* 6/5)*(& (* 1& 3/*& 6123&, 6/* 6/*6(*'+62/*(& 6/*6(*'+62/*(& '/'1(& =)( ;+8* 0( "" #"" 57L. S.A. ""# )* )'/+ 0('11/ =)( 1 @/+5 0( 0)+(3 5?& 6/5* 4+/-1(5?'26 (& 1 6)&0 4/+ 1 4+(&(*62 0( -26+-/*'/ 0( &/02/ C HCO . E1 7) 1 0=)2(+( 6)*0/ 1 11);2 4& 4/+ 42(0+ 6123 CCO . C)*0/ (1 7) 0( 11);2 6( 02&)(1;( 02920/ 0( 6+-/*/ CO 0(1 2+( @/+5 ?620/ 6+-9*26/ H CO, 4/+ 1/ =)( &( 6202@26 127(+5(*'(: CO 7 HO 1 → HCO 6 E1 6+-/*'/ 0( &/02/ CCO */ (& 5) &/1)-1( (* 7), &2* (5-+7/, 6)*0/ (1 ?620/ 021)20/ 4& 4/+ 1 42(0+ 6123 +(662/* @/+5*0/ -26+-/*'/ 0( &/02/ CHCO =)( &8 (& &/1)-1( (* 7): CCO & HCO 6 → C 6 HCO$ 6 P/+ 1/ '*'/, (1 7) 0( 11);2 '/5 2/*(& 6162/ C 2/*(& -26+-/*'/ HCO $ &( ;)(1;( 0)+. C)*0/ (1 7) 0)+ &( 612(*' 1& 0/& +(662/*(& *'(+2/+(& &( +(;2(+'(* &( @/+5 6+-/*'/ 0( 6162/, 7) 02920/ 0( 6+-/*/: C 6 HCO$ 6 → CCO & HO 1 CO 7
E1 6+-/*'/ 0( 6162/ CCO (& 5)6 5(*/& &/1)-1( (* 7) =)( (1 -26+-/*'/ 0( 6162/ CHCO 4/+ 1/ =)( &( 4+(6242' @/+5*0/ )* &9120/ 6/*/620/ 6/5/ &++/, 2*6+)&'62/*(& / 2*6+)&'62/*(& 0( 6162/.
2.4. TIPOS DE DUREZA BOLA, A ""#, (*)5(+ 0/& '24/& 0( 0)+(3, 1/& 6)1(& &/*:
2.4.1. Dure! Te"#$r!% E&' 0('(+52*0 4/+ (1 6/*'(*20/ 0( 6+-/*'/& -26+-/*'/& 0( 6162/ 57*(&2/. P)(0( &(+ (1252*0 4/+ (-)112629* 0(1 7) 4/&'(+2/+ (1252*629* 0( 4+(6242'0/& @/+50/& 4/+ @21'+629*, '5-2>* &( 1( 6/*/6( 6/5/ D)+(3 0( C+-/*'/&.
2.4.2. Dure! Per"!&e&'e E&'? 0('(+52*0 4/+ '/0& 1& &1(& 0( 6162/ 57*(&2/ (6(4'/ 6+-/*'/& -26+-/*'/&. N/ 4)(0( &(+ (1252*0 4/+ (-)112629* 0(1 7) '5-2>* &( 1( 6/*/6( 6/5/ D)+(3 0( N/ 6+-/*'/&.
2.. INTERPRETACIÓN DE LA DUREZA BOLA, BOLA, A ""#, (4+(& =)( &(7* &(7* 1 A5(+26* A5(+26* S/62(' @/+ '(&'2*7 '(&'2*7 *0 M'(+21&, M'(+21&, (&'-1(6( 1 2*'(+4+('629* 0( 1 0)+(3 0( 1 &27)2(*'( 5*(+:
Dure! $"$ C!CO3 "$ $!" !"$"" ""
I&'er#re'!*+& A7) &);( A7) 4/6/ 0)+ A7) 0)+ A7) 5) 0)+
BOLA, A ""#, &(1 =)( (1 7) 4/'-1( '2(*( )* 1852'( 5?25/ 4(+52&2-1( 0( "" 571 0( 0)+(3.
2.,. GRADO HIDROTIMÉTRICOS - ALCALIMÉTRICOS 2.,.1. Gr!$ /*r$'*"0'r*$ BARRAQUÉ, C. ('. 1. !, 2*026* =)( (1 7+0/ <20+/'25>'+26/ TH 2*026 (1 6/*'(*20/ 71/-1 (* &1(& 0( 6162/ 57*(&2/ =)( <6(* 1 7) 0)+. L/& 7+0/&
<20+/5>'+26/& 2*026* 1 6*'200 0( -26+-/*'/&, &)1@'/&, 61/+)+/&, ('6., 0( 1& &1(& 1612*/'>++(& 6/*'(*20& (* (1 7). S( 02&'2*7)( 4+ (11/: ‐
‐
‐
‐
TH '/'1: 2*026 0( )* 5*(+ 71/-1 (1 6/*'(*20/ (* &1(& 0( C M7. TH 6?1626/: 2*026 (1 6/*'(*20/ 71/-1 (* &1(& 0( C D)+(3 6+-/*'0: 2*026 (1 6/*'(*20/ (* <20+/7(*/$6+-/*'/& 6+-/*'/& 0( 6162/ 0( 57*(&2/. D)+(3 */ 6+-/*'0: 2*026 (1 6/*'(*20/ (* &)1@'/& 61/+)+/& 0( 6162/ 57*(&2/. E& 27)1 1 02@(+(*62 0( TH '/'1 % D)+(3 6+-/*'0.
2.,.2. Gr!$ !%!%*"0'r*$ BARRAQUÉ, C. ('. 1. !, 0('11* =)( 1 5(020 0( 1 1612*200 &( (@(6' 6/* )* &/1)629* ;1/+0 0( 620/ (* 4+(&(*62 0( @(*/1@'1(8* 7+0/ 16125>'+26/ &2541( TA / 0( *+*0/ 0( 5('21/ / <(12*'2* 7+0/ 16125>'+26/ 6/541('/ TAC. L/& ;1/+(& TA TAC 2*026* (1 6/*'(*20/ 0(1 7) (* <20+920/&, 6+-/*'0/& / -26+-/*'0/& 1612*/& / 1612*/'>++(/&. 1612*/'>++(/&.
2.. ENEICIO DE LA DUREZA DE UNA AGUA E1 7) 0)+ (& -(*(@262/& (* 7) 0( +2(7/ 4/+=)( 1/& 2/*(& 1612*/'>++(/&, '2(*0(* @1/6 @1/6)1 )1+ + @/+ @/+5 5++ 7+( 7+(7 70/ 0/& & 6/* 6/* 1& 1& 4+' 4+'86 86)1 )1& & 6/1/ 6/1/20 201 1(& (& 0(1 0(1 &)(1 &)(1// , 6/5 6/5/ 6/*&(6)(*62, 6/*&(6)(*62, )5(*' 1 4(+5(-21200 0(1 &)(1/ 1 7).
III. MATERIALES - MÉTODOS 3.1. DETERMINACIÓN DE LA DUREZA TOTAL. 3.1.1. M!'er*!%e ‐
M)(&'+ 0( 7)
‐
B1*3 (1>6'+26
‐
E+1(*5((+
‐
P24(' 7+0)0 0( " 51
‐
A7) 0(&'210
‐
B)+('
‐
S/4/+'( 4+ -)+('
Re!'*5$ ‐
‐
‐
B)@@(+ E+2/6+/5/ *(7+/ T. 2*0260/+ EDTA ", "!M A620/ E'21(* D252*/ T('+ A6>'26/ D2&9026/ 02 <20+'0/
3.1.2. M0'$$ ‐
O-'(*(+ 6/* )* 424(' 7+0)0 " 51 0( )* 5)(&'+ 0( 7), 0(4/&2'+1/& (* )* (+1(*5((+.
‐
A7+(7+ 51 0( )* &)&'*62 -)@@(+, 1 5)(&'+ 4+/-1(5. P+ 1 4+(4+629* 0(1 -)@@(+ &( /-'2(*(* 1/& 4(&/& 0( 1& &)&'*62& 0( 1 &( @/+ "51. "51. E&' &/1)629* &( 6/541(5(*' 6/* 1& &)&'*62& 0( 2 &( @/+ "51
1. !,!7 EDTA ",7 SO #M7.HO "51 2. !,7 C1NH# !#51 NH#OH "51 ‐
A026 A0 262/ 2/* *++ ",#7 ",#7 0( E+2/ E+2/6+ 6+/5 /5// *(7+ *(7+// T ENT ENT, , =)( =)( &( 1/ )'21 )'2123 23 6/5/ 6/5/ )* 2*0260/+. 2*0260/+. C) 4+(4+629* &( 5)(&'+ 6/*'2*)629*. ",7 ENT !""7 C1N
‐
T2')1+ (1 6/*'(*20/ 0(1 (+1(*5((+ 6/* EDTA ","!M, <&' 4)*'/ @2*1 3)1.
‐
D('(+52*+ (1 7&'/ 0( 1 -)+(' 0(1 EDTA, 616)1+ 1 0)+(3 '/'1 0( 1 5)(&'+ 4+/-1(5, 5(02*'( 1 &27)2(*'( @9+5)1:
Dure! '$'!% 6 75$%u"e& e% EDTA 8 29 L 0)+(3, (&'? 00 (* )*200(& 0( 445 CO C
3.2. DETERMINACIÓN DE LA DUREZA DEL CALCIO. 3.2.1. M!'er*!%e ‐
M)(&'+ 0( 7)
‐
B1*3 (1>6'+26
‐
E+1(*5((+
‐
P24(' 7+0)0 0( " 51
‐
A7) 0(&'210
‐
B)+('
‐
S/4/+'( 4+ -)+('
Re!'*5$ ‐
‐
‐
H20+920/ 0( &/02/ NOH M)+(20( 2*0260/+ EDTA ","!M A620/ E'21(* D252*/ T('+ A6>'26/ D2&9026/ 02 <20+'0/
3.2.2. M0'$$ ‐
O-'(*(+ 6/* )* 424(' 7+0)0 " 51 0( )* 5)(&'+ 0( 7), 0(4/&2'+1/& (* )* (+1(*5((+.
‐
‐
A7+(7+ 51 0( <20+920/ 0( &/02/ NOH 1 5)(&'+ 4+/-1(5. A0262/*+ ",#7 0( M)+(20(. L 4+(4+629* 0(1 M)+(20( &( 5)(&'+ 6/*'2*)629*: ",7 M)+(20( !""7 C1N
‐
T2')1+ (1 6/*'(*20/ 0(1 (+1(*5((+ 6/* EDTA ","!M, <&' 4)*'/ @2*1 4)+4)+.
‐
D('(+52*+ (1 7&'/ 0( 1 -)+(' 0(1 EDTA, 616)1+ 1 0)+(3 0(1 6162/ 0( 1 5)(&'+ 4+/-1(5, 5(02*'( 1 &27)2(*'( @9+5)1:
Dure! e% !%*$ 6 75$%u"e& EDTA 8 2:9 L 0)+(3 0(1 6162/ (&' 00/ (* )*200(& 0( 445 CO C
3.3. OTENCIÓN DE LA DUREZA DE MAGNESIO. O-'(*20/& 1/& ;1/+(& 0( 1 0)+(3 '/'1 1 0)+(3 0(1 6162/, &( 0(&4( 1 0)+(3 0(1 57*(&2/ 0( 1 @/+5)1 0( 1 0)+(3 '/'1 0( )* 5)(&'+ 0( 7), 0( 1 &27)2(*'( 5*(+: D)+(3 '/'1 W D)+(3 0(1 6162/ D)+(3 0(1 57*(&2/
Dure! e% "!;&e*$ 6 Dure! '$'!% < Dure! e% !%*$ L 0)+(3 0(1 57*(&2/ (&' 00/ (* )*200(& 0( 445 CO C
IV. RESULTADOS C)0+/ !. D('(+52*629* '/'1 0( 1 0)+(3 0( )* 5)(&'+ 0( 7), (1 !# 0( 0262(5-+( 0(1 "!!.
Lu;!r e %! "ue'r!
V$%u"e& e %! "ue'r!
G!'$ e% EDTA
##" CO3C! '$'!%
A;u! e r*e;$ A;u! #$'!=%e A;u! e #$$
",""51 ",""51 ",""51
,51 ,"51 ,51
!,"" 571' !","" 571' !!!," 571'
C)0+/ . D('(+52*629* 0( 1 0)+(3 0( 1& &1(& 0( 6162/ 0( )* 5)(&'+ 0( 7), (1 !# 0( 0262(5-+( 0(1 "!!.
Lu;!r e %! "ue'r!
V$%u"e& e %! "ue'r!
G!'$ e% EDTA
##" CO3C! !%*$
A;u! e r*e;$ A;u! #$'!=%e A;u! e #$$
",""51 ",""51 ",""51
!,51 #,51 !,"51
,"" ,"" #,""
C)0+/ . O-'(*629* 0( 1 0)+(3 0( 1& &1(& 0( 57*(&2/ 0( )* 5)(&'+ 0( 7), (1 !# 0( 0262(5-+( 0(1 "!!.
Lu;!r e %! "ue'r! A;u! e r*e;$ A;u! #$'!=%e A;u! e #$$
##" CO3C! "!;&e*$
!","" ,"" ,"
Dure! ##" CO3C! !%*$
,"" ,"" #,""
##" CO3C! '$'!%
!,"" !","" !!!,"
I&'er#re'!*+& A7) 0)+ A7) 0)+ A7) 4/6 0)+
D27+5 !. C/54+629* 0( 1 0)+(3 0( 1& &1(& 0( 57*(&2/, 6162/ 0)+(3 '/'1 0( 1& 5)(&'+ 0( 7) )'21230& (* 1 4+?6'26, (1 !# 0( 0262(5-+( 0(1 "!!. 165.0
170.0
130.0 111.8 85.0
35.0
85.0
77.8
34.0
C,162/ A7), 0( 0( +2 +2(7/
M,7*(&2/ A7), 4/ 4/',-1(
D)+(3, '/',1 A7), 0( 0( 4/ 4/3/
V. DISCUSIÓN - CONCLUSIONES .1. DISCUSIONES ‐
L 0)+(3 '/'1 0( 1 5)(&'+ 0(1 7) 0( +2(7/ (& 0( !,"" 445 CO C, &(7* 1 2*'(+4+('629* (&'-1(620 (* 1 +(;2&29* 12'(++2 (& )* 7) 0)+, (&'/ &( 0(-( =)( (& )* 7) &)-'(++?*( =)( 4& '+;>& 0( 1 6123 =)( 02&)(1;( 1/& 6/54)(&'/& 0( 6162/ 57*(&2/ =)( 4+/;/6* 1 0)+(3 (&'/ 6/*11(;+8 4/0(+ 4(+)026+ 1/& 6)1'2;/&.
‐
E* 6)0+/ 1 0)+(3 0(1 6162/ (& 5/+ 1 0)+(3 0(1 57*(&2/ (* (1 7) 0( +2(7/ (* (1 7) 0( 4/3/, (&'& 0/& &2(*0/ 0( /+27(* )* 4/3/ &)-'(++?*(/, 4/+ (*0( (&'& 5)(&'+& &/* 7)& 4+925& &(+ &12*&, 02@(+(*62& 0( 1 5)(&'+ 0(1 7) 4/'-1(, =)( (2&'( )* 27)100 (*'+( 1 0)+(3 0( 6162/ 57*(&2/, =)( &(+8 )* 7) 6&2 */+51. E&'/ &( 0(-( 4+2*62415(*'( 1 0)+(3 0( 6162/, =)( 2*@1)( 02+(6'5(*'( 1 &12*200 0(1 7).
.2. CONCLUSIONES ‐
L& 7)& &)-'(++?*(& '2(*0(* &(+ 0)+& =)( 4&* '+;>& 0( 1 6123 =)( 02&)(1;( 1/& 6/54)(&'/& 0( 6162/ 57*(&2/ =)( 4+/;/6* 1 0)+(3.
‐
C)*0/ 1 0)+(3 0( 6162/ (& 5/+ 1 0)+(3 0( 57*(&2/, &( 4)(0( (&4(62@26+ =)( (& )* 7) */+51, 52(*'+& =)( &2 1 0)+(3 0( 57*(&2/ (& 5/+ 1 0)+(3 0( 6162/ &( 5*2@2(&' =)( (& )* 7) 4+925 &(+ &12*.
VI. ILIOGRA>A !. BARRAQ BARRAQUÉ, UÉ, C. ('. 1. !. !. M*)1 M*)1 0(1 7) 7). . E&4. E&4. E02'/+ E02'/+21 21 G+@/. G+@/. S.A. P?7&.: $. . BARRO BARRO,, G. !. !. Q)8526 Q)8526 7(*(+1, 7(*(+1, '/5/ '/5/ I. E02'/+21 E02'/+21 R(;(+'>. R(;(+'>. P?7&.: P?7&.: !$ . BOLA BOLA,, A. ""# ""#.. A*?12 *?12&2 &2&& 0( 0)+( 0)+(3 3 0( 7) 7)&. &. R(6) R(6)4( 4(+ +0/ 0/ (1 " 0( 0262(5-+(
0(1
"!!
0(
1
472*
X(-:
<''4:+')+/-/1.'+24/0.6/50)+(3.<'5. #. IIGUE IIGUE, , M. !. !. M*(/ M*(/ 6/* 6/*&(+ &(+;6 ;629* 29* 0( &)(1/& &)(1/& 7)&. 7)&. E6)0/ E6)0/++ % L/. E02'/+21 C/&5/&. P?7&.: !. . KENJ KENJIN INS, S, D. ('. ('. 1. 1. ! !.. Q) Q)85 8526 26 0(1 0(1 7) 7),, 5*) 5*)1 1 0( 1-/ 1-/+ +'/ '/+2 +2/. /. M>26/. E02'/+21 L25)& S.A. P?7&.: $!. . JIELY JIELY, G. !. I*7(*2(+8 I*7(*2(+8 5-2(*' 5-2(*'1,1, @)*05(*'/&, @)*05(*'/&, '(6*/1/78 '(6*/1/78&& &2&'(5& &2&'(5& 0( 7(&'29*. C/1/5-2. E02'/+21 N/5/&. P?7&.: , , ", !. . JIMM JIMMER ER,, F M6CA M6CALL LLIO ION, N, K. !. !. M*) M*)1 1 0(1 0(1 7) 7),, &) *')+ *')+1( 1(3 3,, '+'52(*'/ 412662/*(&. M>26/. E02'/+21 C+;1 S.A. S(6629*.: #$!, #$ #. . S.A. S.A. ""# ""#.. I*'+ I*'+/0 /0)6 )662 629* 9* 1 D) D)+( +(3 3 0(1 0(1 A7). 7). R(6) R(6)4( 4(+ +0/ 0/ (1 0( 0262(5-+(
0(1
"!!
0(
<''4:XXX.5(7/3/*/.6/50)+(3.<'5.
1
472*
X(-: